With the ladder operators, you can determine how different angular momenta add up to net angular momentum. As an example, this section will examine what net spin values can be produced by two particles, each with spin . They may be the proton and electron in a hydrogen atom, or the two electrons in the hydrogen molecule, or whatever. The actual result will be to rederive the triplet and singlet states described in chapter 5.5.6, but it will also be an example for how more complex angular momentum states can be combined.
The particles involved will be denoted as and . Since
each particle can have two different spin states and
, there are four different combined
The angular momentum in the -direction is simple; it is just the sum of those of the individual particles. For example, the -momentum of the state follows from
The net total angular momentum is not so obvious; you cannot just add
total angular momenta. To figure out the total angular momentum of
anyway, there is a trick: multiply it with the
combined step-up operator
Here is another trick: multiply by : that will go one step down the combined states ladder and produce a combination state :
But this gives only one combination state for the two product states and with zero net -momentum. If you want to describe unequal combinations of them, like by itself, it cannot be just a multiple of . This suggests that there may be another combination state involved here. How do you get this second state?
Well, you can reuse the first trick. If you construct a combination
of the two product states that steps up to zero, it must be a state
with zero angular momentum that is at the end of its ladder, a
state. Consider an arbitrary combination of the two
product states with as yet unknown numerical coefficients and
To find the remaining triplet state,
just apply once more, to above. It gives:
Figure 12.3 shows the results graphically in terms of ladders. The two possible spin states of each of the two electrons produce 4 combined product states indicated using up and down arrows. These product states are then combined to produce triplet and singlet states that have definite values for both and total net angular momentum, and can be shown as rungs on ladders.
Note that a product state like cannot be shown
as a rung on a ladder. In fact, from adding (12.12) and
(12.13) it is seen that